Download Adhesion Aspects of Polymeric Coatings by K.L. Mittal PDF

By K.L. Mittal

ISBN-10: 1461336600

ISBN-13: 9781461336600

This quantity chronicles the lawsuits of the Symposium on Adhesion facets of Polymeric Coatings held lower than the auspices of the Electrochemical Society in Minneapolis, MN, might 10-15, 1981. This occasion was once cosponsored via the Dielectric and Insulation, and Electrothermics and Metallurgy Divisions. Polymeric coatings are used for a couple of reasons, e. g. , ornamental, protecting, sensible (as dielectrics or insulators) and a distinct software of polymeric (organic) coatings is their use as lithographic fabrics for making built-in circuit components. regardless of the aim of the coating, it needs to adhere good to the underlying substrate. So the necessity to below­ stand the criteria which impact adhesion of natural coatings and the how you can reach wanted adhesion is sort of appear. This Symposium was once designed to assemble scientists and technologists drawn to the adhesion elements of polymeric coatings, to supply a discussion board for dialogue of contemporary findings, and to supply a chance for cross-pollination of rules. The technical software contained a complete of forty six papers through authors from a variety of corners of the realm. this system comprised either invited overviews and contributed unique examine papers, as this combination is tips on how to current the country of data of an issue. The invited audio system have been chosen for you to signify commonly fluctuate­ ing disciplines and pursuits they usually hailed from a number of aca­ demic and business learn laboratories.

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Surface, the penetration of adhesive into the pores must be beneficial. As Bascom says "the resin-metal oxide composite interphase would contribute significantly to bond durability"78. ROLE OF SURFACE TOPOGRAPHY 35 Figure 6. 55 Figure 7. Scanning electron micrograph of the surface of copper oxidized at 90 0 e in "Ebonol e" solution for 10 minutes. 91 36 D. E. -. ~ . -. "uce" 011:10. 10 20 30 cnpper oxidation Ii me (minutes) IJJ Figure 8. Adhesion of polyethylene to copper oxidized in alkaline chlorite solution 91 The effect of time in oxidizing solution prior to bonding.

Vaishnav, J. Adhesion, l, 215 (1975). W. D. Bascom, C. O. Timmons and R. L. Jones, J. , 10, 1037 (1975). W. D. Bascom and J. Oroshnik, J. , 13, i411 (1978). -F. Keller, M. S. Hunter and D. L. Robinson, J. Electrochem. , 100, 411 (1953). J. P. O'Sullivan and G. C. Wood, Proc. Roy. , A317, 511 (1970) B. W. Malpass, D. E. Packham and K. Bright. J. Appl. Polym. , 18, 3249 (1974). S. Ahearn, G. D. Davis, T. S. Sun and J. D. Venables, this proceedings volume. J. D. Venables, D. K. McNamara, J. M. Chen and T.

55 Figure 7. Scanning electron micrograph of the surface of copper oxidized at 90 0 e in "Ebonol e" solution for 10 minutes. 91 36 D. E. -. ~ . -. "uce" 011:10. 10 20 30 cnpper oxidation Ii me (minutes) IJJ Figure 8. Adhesion of polyethylene to copper oxidized in alkaline chlorite solution 91 The effect of time in oxidizing solution prior to bonding. Top curve: polymer applied to the original matt black oxide. Bottom curve: oxide reduced to copper before application of the polymer. Surfaces with Fibre-like Topography It has long been known that copper (and some of its alloys) can be oxidized in aqueous solutions to give a matt black oxide layer.

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